Colorful Electrochromic Displays with High Visual Quality Based on Porous Metamaterials.

The introduction of metamaterials into electrochromic (EC) displays has recently inspired a great breakthrough in the EC field, as this can offer a variety of new attractive features, from a very wide gamut of colors to very fast switching times. However, such metamaterial-based EC displays still face significant constraints when developing from single electrodes to full devices, because other supportive components in devices, such as counter electrodes and electrolytes, significantly affect light propagation and the subsequent perceived color quality in metamaterial-based EC devices. Herein, a new, cost-effective device design structured around a new type of porous metamaterial is reported to circumvent the critical problem in metamaterial-based EC displays. Owing to its unique design, the metamaterial-based EC device achieves good color quality with no drop in brightness or shift in color chromaticity when compared with a single electrode. Moreover, the porous-metamaterial-based EC device can exhibit non-iridescence and be viewed from a wide range of angles (5°-85°) and has fast switching response (2.4 and 2.5 s for coloration and bleaching, respectively), excellent cycling performance (at least 2000 cycles), and extremely low power consumption (4.0 mW cm-2 ).

Semiconductor SERS on Colourful Substrates with Fabry-Pérot Cavities.

Non-metallic materials have emerged as a new family of active substrates for surface-enhanced Raman scattering (SERS), with unique advantages over their metal counterparts. However, owing to their inefficient interaction with the incident wavelength, the Raman enhancement achieved with non-metallic materials is considerably lower with respect to the metallic ones. Herein, we propose colourful semiconductor-based SERS substrates for the first time by utilizing a Fabry-Pérot cavity, which realize a large freedom in manipulating light. Owing to the delicate adjustment of the absorption in terms of both frequency and intensity, resonant absorption can be achieved with a variety of non-metal SERS substrates, with the sensitivity further enhanced by ≈100 times. As a typical example, by introducing a Fabry-Pérot-type substrate fabricated with SiO2 /Si, a rather low detection limit of 10-16  M for the SARS-CoV-2S protein is achieved on SnS2 . This study provides a realistic strategy for increasing SERS sensitivity when semiconductors are employed as SERS substrates.